A Hexaimidazole Ligand Binding Six Octahedral Metal Ions To Give an Infinite 3D α-Po-Like Network Through Which Two Independent 2D Hydrogen-Bonded Networks Interweave

A Hexaimidazole Ligand Binding Six Octahedral Metal Ions To Give an Infinite 3D α-Po-Like Network Through Which Two Independent 2D Hydrogen-Bonded Networks Interweave

The new ligand hexakis(imidazol‐1‐ylmethyl)benzene (hkimb, 1) forms a heavily hydrated coordination polymer with CdF2 of composition Cd(hkimb)F2 · 14 H2O. A unique aspect of the structure is that the water assembles itself into two independent and different hydrogen‐bonded 2D networks, which interwe...

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Veröffentlicht in:Angewandte Chemie International Edition 1997-01, Vol.36 (24), p.2752-2755
Hauptverfasser: Hoskins, Bernard F., Robson, Richard, Slizys, Damian A.
Format: Artikel
Sprache:eng
Schlagworte:
cadmium
coordination polymers
crystal engineering
hydrogen bonds
imidazole
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Zusammenfassung:The new ligand hexakis(imidazol‐1‐ylmethyl)benzene (hkimb, 1) forms a heavily hydrated coordination polymer with CdF2 of composition Cd(hkimb)F2 · 14 H2O. A unique aspect of the structure is that the water assembles itself into two independent and different hydrogen‐bonded 2D networks, which interweave throughout the 3D α‐Po‐related coordination polymer network.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199727521