Enantiomerically Pure "Winged" Spirane Porphyrazinoctaols

Enantiomerically Pure "Winged" Spirane Porphyrazinoctaols

Macrocyclization of 2,3‐dicyano‐1,4‐diox‐2‐ene with magnesium propoxide in propanol provided the enantiomerically pure C4‐symmetric (porphyrazinato)magnesium(II) complex 1. The structure of the macrocycle was confirmed by an X‐ray crystallographic study on the demetalated porphyrazine.

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Veröffentlicht in:Angewandte Chemie International Edition 1997-04, Vol.36 (7), p.760-761
Hauptverfasser: Cook, Andrew S., Williams, D. Bradley G., White, Andrew J. P., Williams, David J., Lange, Steven J., Barrett, Anthony G. M., Hoffman, Brian M.
Format: Artikel
Sprache:eng
Schlagworte:
chirality
cyclic voltammetry
porphyrinoids
protecting groups
spiro compounds
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Zusammenfassung:Macrocyclization of 2,3‐dicyano‐1,4‐diox‐2‐ene with magnesium propoxide in propanol provided the enantiomerically pure C4‐symmetric (porphyrazinato)magnesium(II) complex 1. The structure of the macrocycle was confirmed by an X‐ray crystallographic study on the demetalated porphyrazine.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199707601