Synthesis and Structure of a Dimeric Peralkylated Hexaaminobenzene: Hexakis(dimethylamino)hexamethyl-hexaaza[63] (1,3,5)cyclophane

Synthesis and Structure of a Dimeric Peralkylated Hexaaminobenzene: Hexakis(dimethylamino)hexamethyl-hexaaza[63] (1,3,5)cyclophane

Increasing the reorganization energy slows intramolecular electron transfer (ET) in 1, a compound thus well‐suited for studying the kinetics of ET processes. A surprisingly smooth, threefold nucleophilic aromatic substitution reaction is the key step in the synthesis of 1.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 1997-04, Vol.36 (6), p.621-623
Hauptverfasser: Wolff, J. Jens, Zietsch, Andreas, Irngartinger, Hermann, Oeser, Thomas
Format: Artikel
Sprache:eng
Schlagworte:
amines
cyclophanes
electron transfer
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 623
container_issue 6
container_start_page 621
container_title Angewandte Chemie International Edition
container_volume 36
creator Wolff, J. Jens
Zietsch, Andreas
Irngartinger, Hermann
Oeser, Thomas
description Increasing the reorganization energy slows intramolecular electron transfer (ET) in 1, a compound thus well‐suited for studying the kinetics of ET processes. A surprisingly smooth, threefold nucleophilic aromatic substitution reaction is the key step in the synthesis of 1.
doi_str_mv 10.1002/anie.199706211
format Article
fullrecord <record><control><sourceid>istex_cross</sourceid><recordid>TN_cdi_crossref_primary_10_1002_anie_199706211</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ark_67375_WNG_TVPQR3RC_X</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3061-a78792095c38fa41ae22a6efbec39b19128865f438a553e86516ea1636748ca33</originalsourceid><addsrcrecordid>eNqFkMtLw0AQxhdRsD6unnNUMHU30-wm3qQ-WhDfLxBZptsJWZumshux6dG_3NSIePM0M998v4H5GNsRvCs4jw6wtNQVaaq4jIRYYR0RRyIEpWCVdXiseMgTgHW24f1r408SLjvs87Yuq5y89QGW4-C2cu-mencUzLIAg2M7JWdNcEUOi0ldYEXjYEBzxKktZyMqF1TS4bcysX533NirvLEtt3t5o7ZzuGxxgc8SXoJdsQ_78Z6pTTF7y7GkLbaWYeFp-6dusvvTk7v-IDy_PBv2j85DA1yKEFWi0oinsYEkw55AiiKUlI3IQDoSqWg-knHWgwTjGKjphSQUEqTqJQYBNlm3vWvczHtHmX5zdoqu1oLrZYJ6maD-TbAB0hb4sAXV_7j10cXw5C8btqz1Fc1_WXQTLRWoWD9enOm7h6vrG7jp6yf4AuPuhg0</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Synthesis and Structure of a Dimeric Peralkylated Hexaaminobenzene: Hexakis(dimethylamino)hexamethyl-hexaaza[63] (1,3,5)cyclophane</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Wolff, J. Jens ; Zietsch, Andreas ; Irngartinger, Hermann ; Oeser, Thomas</creator><creatorcontrib>Wolff, J. Jens ; Zietsch, Andreas ; Irngartinger, Hermann ; Oeser, Thomas</creatorcontrib><description>Increasing the reorganization energy slows intramolecular electron transfer (ET) in 1, a compound thus well‐suited for studying the kinetics of ET processes. A surprisingly smooth, threefold nucleophilic aromatic substitution reaction is the key step in the synthesis of 1.</description><identifier>ISSN: 0570-0833</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.199706211</identifier><language>eng</language><publisher>Zug: Hüthig &amp; Wepf Verlag</publisher><subject>amines ; cyclophanes ; electron transfer</subject><ispartof>Angewandte Chemie International Edition, 1997-04, Vol.36 (6), p.621-623</ispartof><rights>Copyright © 1997 by VCH Verlagsgesellschaft mbH, Germany</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3061-a78792095c38fa41ae22a6efbec39b19128865f438a553e86516ea1636748ca33</citedby><cites>FETCH-LOGICAL-c3061-a78792095c38fa41ae22a6efbec39b19128865f438a553e86516ea1636748ca33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.199706211$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.199706211$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,778,782,1414,27911,27912,45561,45562</link.rule.ids></links><search><creatorcontrib>Wolff, J. Jens</creatorcontrib><creatorcontrib>Zietsch, Andreas</creatorcontrib><creatorcontrib>Irngartinger, Hermann</creatorcontrib><creatorcontrib>Oeser, Thomas</creatorcontrib><title>Synthesis and Structure of a Dimeric Peralkylated Hexaaminobenzene: Hexakis(dimethylamino)hexamethyl-hexaaza[63] (1,3,5)cyclophane</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed. Engl</addtitle><description>Increasing the reorganization energy slows intramolecular electron transfer (ET) in 1, a compound thus well‐suited for studying the kinetics of ET processes. A surprisingly smooth, threefold nucleophilic aromatic substitution reaction is the key step in the synthesis of 1.</description><subject>amines</subject><subject>cyclophanes</subject><subject>electron transfer</subject><issn>0570-0833</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1997</creationdate><recordtype>article</recordtype><recordid>eNqFkMtLw0AQxhdRsD6unnNUMHU30-wm3qQ-WhDfLxBZptsJWZumshux6dG_3NSIePM0M998v4H5GNsRvCs4jw6wtNQVaaq4jIRYYR0RRyIEpWCVdXiseMgTgHW24f1r408SLjvs87Yuq5y89QGW4-C2cu-mencUzLIAg2M7JWdNcEUOi0ldYEXjYEBzxKktZyMqF1TS4bcysX533NirvLEtt3t5o7ZzuGxxgc8SXoJdsQ_78Z6pTTF7y7GkLbaWYeFp-6dusvvTk7v-IDy_PBv2j85DA1yKEFWi0oinsYEkw55AiiKUlI3IQDoSqWg-knHWgwTjGKjphSQUEqTqJQYBNlm3vWvczHtHmX5zdoqu1oLrZYJ6maD-TbAB0hb4sAXV_7j10cXw5C8btqz1Fc1_WXQTLRWoWD9enOm7h6vrG7jp6yf4AuPuhg0</recordid><startdate>19970404</startdate><enddate>19970404</enddate><creator>Wolff, J. Jens</creator><creator>Zietsch, Andreas</creator><creator>Irngartinger, Hermann</creator><creator>Oeser, Thomas</creator><general>Hüthig &amp; Wepf Verlag</general><scope>BSCLL</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>19970404</creationdate><title>Synthesis and Structure of a Dimeric Peralkylated Hexaaminobenzene: Hexakis(dimethylamino)hexamethyl-hexaaza[63] (1,3,5)cyclophane</title><author>Wolff, J. Jens ; Zietsch, Andreas ; Irngartinger, Hermann ; Oeser, Thomas</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3061-a78792095c38fa41ae22a6efbec39b19128865f438a553e86516ea1636748ca33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1997</creationdate><topic>amines</topic><topic>cyclophanes</topic><topic>electron transfer</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wolff, J. Jens</creatorcontrib><creatorcontrib>Zietsch, Andreas</creatorcontrib><creatorcontrib>Irngartinger, Hermann</creatorcontrib><creatorcontrib>Oeser, Thomas</creatorcontrib><collection>Istex</collection><collection>CrossRef</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wolff, J. Jens</au><au>Zietsch, Andreas</au><au>Irngartinger, Hermann</au><au>Oeser, Thomas</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Structure of a Dimeric Peralkylated Hexaaminobenzene: Hexakis(dimethylamino)hexamethyl-hexaaza[63] (1,3,5)cyclophane</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. Chem. Int. Ed. Engl</addtitle><date>1997-04-04</date><risdate>1997</risdate><volume>36</volume><issue>6</issue><spage>621</spage><epage>623</epage><pages>621-623</pages><issn>0570-0833</issn><eissn>1521-3773</eissn><abstract>Increasing the reorganization energy slows intramolecular electron transfer (ET) in 1, a compound thus well‐suited for studying the kinetics of ET processes. A surprisingly smooth, threefold nucleophilic aromatic substitution reaction is the key step in the synthesis of 1.</abstract><cop>Zug</cop><pub>Hüthig &amp; Wepf Verlag</pub><doi>10.1002/anie.199706211</doi><tpages>3</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0570-0833
ispartof Angewandte Chemie International Edition, 1997-04, Vol.36 (6), p.621-623
issn 0570-0833
1521-3773
language eng
recordid cdi_crossref_primary_10_1002_anie_199706211
source Wiley Online Library Journals Frontfile Complete
subjects amines
cyclophanes
electron transfer
title Synthesis and Structure of a Dimeric Peralkylated Hexaaminobenzene: Hexakis(dimethylamino)hexamethyl-hexaaza[63] (1,3,5)cyclophane
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-15T20%3A22%3A32IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-istex_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Synthesis%20and%20Structure%20of%20a%20Dimeric%20Peralkylated%20Hexaaminobenzene:%20Hexakis(dimethylamino)hexamethyl-hexaaza%5B63%5D%20(1,3,5)cyclophane&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.au=Wolff,%20J.%20Jens&rft.date=1997-04-04&rft.volume=36&rft.issue=6&rft.spage=621&rft.epage=623&rft.pages=621-623&rft.issn=0570-0833&rft.eissn=1521-3773&rft_id=info:doi/10.1002/anie.199706211&rft_dat=%3Cistex_cross%3Eark_67375_WNG_TVPQR3RC_X%3C/istex_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true