Synthesis and Structure of a Dimeric Peralkylated Hexaaminobenzene: Hexakis(dimethylamino)hexamethyl-hexaaza[63] (1,3,5)cyclophane

Synthesis and Structure of a Dimeric Peralkylated Hexaaminobenzene: Hexakis(dimethylamino)hexamethyl-hexaaza[63] (1,3,5)cyclophane

Increasing the reorganization energy slows intramolecular electron transfer (ET) in 1, a compound thus well‐suited for studying the kinetics of ET processes. A surprisingly smooth, threefold nucleophilic aromatic substitution reaction is the key step in the synthesis of 1.

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Veröffentlicht in:Angewandte Chemie International Edition 1997-04, Vol.36 (6), p.621-623
Hauptverfasser: Wolff, J. Jens, Zietsch, Andreas, Irngartinger, Hermann, Oeser, Thomas
Format: Artikel
Sprache:eng
Schlagworte:
amines
cyclophanes
electron transfer
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Beschreibung
Zusammenfassung:Increasing the reorganization energy slows intramolecular electron transfer (ET) in 1, a compound thus well‐suited for studying the kinetics of ET processes. A surprisingly smooth, threefold nucleophilic aromatic substitution reaction is the key step in the synthesis of 1.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199706211