Transition Metal Germylene Complexes as Hydrogenation Catalysts: The Synthesis of a Rare Bis(amino)germane

Mild conditions avoid the common problem of GeN bond scission in the stoichiometric and catalytic synthesis of a rare example of a stable bis(amino)germane from Group 10 metal–germylene complexes [Eq. (a), R = Et, Ph]. The reaction generates an interesting GeH2 building block.

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Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie International Edition 1997-03, Vol.36 (5), p.496-498
Hauptverfasser:	Litz, Kyle E., Bender IV, John E., Kampf, Jeff W., Holl, Mark M. Banaszak
Format:	Artikel
Sprache:	eng
Schlagworte:	germanium hydrogenations nickel platinum
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Mild conditions avoid the common problem of GeN bond scission in the stoichiometric and catalytic synthesis of a rare example of a stable bis(amino)germane from Group 10 metal–germylene complexes [Eq. (a), R = Et, Ph]. The reaction generates an interesting GeH2 building block.
ISSN:	0570-0833 1521-3773
DOI:	10.1002/anie.199704961