Synthesis and Characterization of the Stable Dicarbonyl(cyclopentadienyl)iron Radical [(C5R5)Fe(CO)2] (R  CHMe2)

Synthesis and Characterization of the Stable Dicarbonyl(cyclopentadienyl)iron Radical [(C5R5)Fe(CO)2] (R  CHMe2)

Monomeric in solution, dimeric in the crystal is the dicarbonyl(pentaisopropyl‐cyclopentadienyl)iron(I) radical 2, which is formed from the high‐spin iron(II) complex 1 by carbonylation and reduction.

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Veröffentlicht in:Angewandte Chemie International Edition 1996-12, Vol.35 (23-24), p.2872-2875
Hauptverfasser: Sitzmann, Helmut, Dezember, Thomas, Kaim, Wolfgang, Baumann, Frank, Stalke, Dietmar, Kärcher, Joerg, Dormann, Elmar, Winter, Hubert, Wachter, Christoph, Kelemen, Marc
Format: Artikel
Sprache:eng
Schlagworte:
cyclopentadienyl complexes
high-spin complexes
iron compounds
radicals
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Beschreibung
Zusammenfassung:Monomeric in solution, dimeric in the crystal is the dicarbonyl(pentaisopropyl‐cyclopentadienyl)iron(I) radical 2, which is formed from the high‐spin iron(II) complex 1 by carbonylation and reduction.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199628721