Hexaaryltellurium, the First Neutral Compounds Comprising Hexaarylated Elements

The highest possible oxidation state of +6 is displayed by the tellurium center in the hexaaryltellurium compounds 1 a and 1 b. Both are extremely thermally stable and, unlike other organotellurium compounds, not light‐sensitive. X‐ray crystallographic analyses of 1 revealed rare examples of approxi...

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Veröffentlicht in:Angewandte Chemie International Edition 1996-12, Vol.35 (22), p.2660-2662
Hauptverfasser: Minoura, Mao, Sagami, Takao, Akiba, Kin-ya, Modrakowski, Claudia, Sudau, Allexander, Seppelt, Konrad, Wallenhauer, Stephan
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Sprache:eng
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Zusammenfassung:The highest possible oxidation state of +6 is displayed by the tellurium center in the hexaaryltellurium compounds 1 a and 1 b. Both are extremely thermally stable and, unlike other organotellurium compounds, not light‐sensitive. X‐ray crystallographic analyses of 1 revealed rare examples of approximate Th molecular symmetry.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199626601