New Cobalt- and Iron-Catalyzed Reactions of Organozinc compounds

New Cobalt- and Iron-Catalyzed Reactions of Organozinc compounds

A wide range of polyfunctional ketones and allylic compounds is accessible under mild reaction conditions through an efficient CoII‐catalyzed acylation or allylation of diorganozinc compounds (see below). The remarkable stability of the intermediate σ‐alkyl transition metal complexes is crucial for...

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Veröffentlicht in:Angewandte Chemie International Edition 1996-08, Vol.35 (15), p.1700-1701
Hauptverfasser: Reddy, C. Kishan, Knochel, Paul
Format: Artikel
Sprache:eng
Schlagworte:
acylations
allylations
catalysis
cobalt compounds
zinc compounds
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Beschreibung
Zusammenfassung:A wide range of polyfunctional ketones and allylic compounds is accessible under mild reaction conditions through an efficient CoII‐catalyzed acylation or allylation of diorganozinc compounds (see below). The remarkable stability of the intermediate σ‐alkyl transition metal complexes is crucial for the success of the reactions.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199617001