An Alkylperoxoiron(III) Intermediate and Its Role in the Oxidation of Aliphatic CH Bonds

An Alkylperoxoiron(III) Intermediate and Its Role in the Oxidation of Aliphatic CH Bonds

Based on EPR, Raman, and mass spectral evidence, the formula 1 best describes the transient intermediate which forms upon treatment of 2 with tert‐butyl hydroperoxide in the presence of alcohol. Kinetic evidence suggests that its decomposition by oxidation of the bound alcohol proceeds via the trans...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 1995-10, Vol.34 (18), p.2048-2051
Hauptverfasser: Kim, Jinheung, Larka, Edmund, Wilkinson, Elizabeth C., Que Jr, Lawrence
Format: Artikel
Sprache:eng
Schlagworte:
CH activation
iron compounds
mass spectrometry
peroxo complexes
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Based on EPR, Raman, and mass spectral evidence, the formula 1 best describes the transient intermediate which forms upon treatment of 2 with tert‐butyl hydroperoxide in the presence of alcohol. Kinetic evidence suggests that its decomposition by oxidation of the bound alcohol proceeds via the transition state 3. tpa = tris(2‐pyridylmethyl)amine.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199520481