Electrochemical Evidence for Through-Space Orbital Interactions in Spiromethanofullerenes

Electrochemical Evidence for Through-Space Orbital Interactions in Spiromethanofullerenes

The electron‐accepting properties of the unsaturated spiromethanofullerene 1 are enhanced relative to those of the saturated analogue with a cyclohexanone unit and of C60. This can be attributed to through‐space interactions between the addend and the carbon cluster.

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Veröffentlicht in:Angewandte Chemie International Edition 1995-08, Vol.34 (15), p.1591-1594
Hauptverfasser: Eiermann, Matthias, Haddon, Robert C., Knight, Brian, Li, Q. Chan, Maggini, Michele, Martín, Nazario, Ohno, Toshinobu, Prato, Maurizio, Suzuki, Toshiyasu, Wudl, Fred
Format: Artikel
Sprache:eng
Schlagworte:
electrochemistry
fullerenes
through-space interactions
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Zusammenfassung:The electron‐accepting properties of the unsaturated spiromethanofullerene 1 are enhanced relative to those of the saturated analogue with a cyclohexanone unit and of C60. This can be attributed to through‐space interactions between the addend and the carbon cluster.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199515911