Bis(hypersilyl)tin and Bis(hypersilyl)lead, Two Electron-Rich Carbene Homologs

Bis(hypersilyl)tin and Bis(hypersilyl)lead, Two Electron-Rich Carbene Homologs

A strongly twisted distannene (shown on the right) is found in crystals of bis(hypersilyl)tin 1. In its violetbrown solutions 1 is mainly monomeric, as is the blue bis(hypersilyl)lead 2.

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Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 1995-07, Vol.34 (12), p.1334-1336
Hauptverfasser: Klinkhammer, Karl Wihelm, Schwarz, Wolfgang
Format: Artikel
Sprache:eng
Schlagworte:
distannenes
hypersily derivatives
plumbylenes
stannylenes
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Beschreibung
Zusammenfassung:A strongly twisted distannene (shown on the right) is found in crystals of bis(hypersilyl)tin 1. In its violetbrown solutions 1 is mainly monomeric, as is the blue bis(hypersilyl)lead 2.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199513341