(DTEDT)[Au(CN)2]0.4: An Organic Superconductor Based on the Novel π-Electron Framework of Vinylogous Bis-Fused Tetrathiafulvalene

(DTEDT)[Au(CN)2]0.4: An Organic Superconductor Based on the Novel π-Electron Framework of Vinylogous Bis-Fused Tetrathiafulvalene

Below 4 K the [Au(CN)2] salt of the radical cation of 1 shows superconductivity. The X‐ray structure analysis reveals that this salt has a two‐dimensional array of donors. The relatively large interactions between the stacks result in a closed Fermi surface.

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Veröffentlicht in:Angewandte Chemie International Edition 1995-06, Vol.34 (11), p.1222-1225
Hauptverfasser: Misaki, Yohji, Higuchi, Natsuko, Fujiwara, Hideki, Yamabe, Tokio, Mori, Takehiko, Mori, Hatsumi, Tanaka, Shoji
Format: Artikel
Sprache:eng
Schlagworte:
organic conductors
superconductors
tetrathiafulvalenes
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Beschreibung
Zusammenfassung:Below 4 K the [Au(CN)2] salt of the radical cation of 1 shows superconductivity. The X‐ray structure analysis reveals that this salt has a two‐dimensional array of donors. The relatively large interactions between the stacks result in a closed Fermi surface.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199512221