Biomimetic Model for a Photosynthetic Reaction Center: A Porphyrin with a Covalently Linked, Redox-Active Crown Ether

A flexible tetramethylene spacer covalently links the porphyrin and quinone moieties in 1. The (photo chemical) properties of this system can be selectively modified by complexation of the crown ether fragment or by incorporation of the molecule in an anisotropic medium.

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Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie International Edition 1994-12, Vol.33 (22), p.2318-2320
Hauptverfasser:	Sun, Licheng, von Gersdorff, Jörg, Niethammer, Dominique, Tian, Peizhu, Kurreck, Harry
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A flexible tetramethylene spacer covalently links the porphyrin and quinone moieties in 1. The (photo chemical) properties of this system can be selectively modified by complexation of the crown ether fragment or by incorporation of the molecule in an anisotropic medium.
ISSN:	0570-0833 1521-3773
DOI:	10.1002/anie.199423181