A Triosmium Cluster Complex with a Carbene Ligand in an Unusual Coordination Mode

The face‐capping carbene ligand displays a chairlike conformation and unusual side‐on bonding in the triosmium cluster 1. This air‐stable compound reacts in the presence of Lewis bases with atmospheric oxygen to form 2, in which the cyclohexadienone ligand is coordinated in a new mode to the Os3 fra...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 1994-06, Vol.33 (10), p.1093-1094
Hauptverfasser:	Edwards, Andrew J., Gallop, Mark A., Johnson, Brian F. G., Köhler, Jochem U., Lewis, Jack, Raithby, Paul R.
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbonyl and nitrosyl compounds, and their complexes Carbonyl and nitrosyl metals Chemistry Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Inorganic chemistry and origins of life Inorganic compounds Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids
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Beschreibung
Zusammenfassung:	The face‐capping carbene ligand displays a chairlike conformation and unusual side‐on bonding in the triosmium cluster 1. This air‐stable compound reacts in the presence of Lewis bases with atmospheric oxygen to form 2, in which the cyclohexadienone ligand is coordinated in a new mode to the Os3 framework.
ISSN:	0570-0833 1521-3773
DOI:	10.1002/anie.199410931