Organoplatinum Dendrimers Formed by Oxidative Addition

A Pt14 dendrimer is the highest nuclearity complex obtained by the first convergent method for the synthesis of alkyl transition metal dendrimers. The product of the first growth cycle is 1, which forms by oxidative addition of 4,4′‐bis(bromomethyl)‐2,2′‐bi‐pyridine to [Me2Pt(tBu2bpy)] and subsequen...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 1994-05, Vol.33 (8), p.847-849
Hauptverfasser:	Achar, Sudhir, Puddephatt, Richard J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Coordination compounds Exact sciences and technology Inorganic chemistry and origins of life Preparations and properties
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A Pt14 dendrimer is the highest nuclearity complex obtained by the first convergent method for the synthesis of alkyl transition metal dendrimers. The product of the first growth cycle is 1, which forms by oxidative addition of 4,4′‐bis(bromomethyl)‐2,2′‐bi‐pyridine to [Me2Pt(tBu2bpy)] and subsequent introduction of a PtII center with [Pt2Me4‐(μ‐SMe2)].
ISSN:	0570-0833 1521-3773
DOI:	10.1002/anie.199408471