A Stannanediyl with a TinCarbon Multiple Bond

A Stannanediyl with a TinCarbon Multiple Bond

A novel ligand coupling reaction on a low‐coordinate Sn atom occurs in the reaction of the ketene ylide 2 with the stannanediyl 1 (R = 2,4,6‐(CF3)C6H2) almost quantitatively to give 3. The SnC distances in 3 suggest a SnC multiple bond in the central planar CCPSnC framework.

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Veröffentlicht in:Angewandte Chemie (International ed.) 1994-03, Vol.33 (4), p.456-458
Hauptverfasser: Grützmacher, Hansjörg, Deck, Werner, Pritzkow, Hans, Sander, Michael
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
Ge, sn, pb derivatives
Organic chemistry
Organometalloidal and organometallic compounds
Preparations and properties
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container_end_page 458
container_issue 4
container_start_page 456
container_title Angewandte Chemie (International ed.)
container_volume 33
creator Grützmacher, Hansjörg
Deck, Werner
Pritzkow, Hans
Sander, Michael
description A novel ligand coupling reaction on a low‐coordinate Sn atom occurs in the reaction of the ketene ylide 2 with the stannanediyl 1 (R = 2,4,6‐(CF3)C6H2) almost quantitatively to give 3. The SnC distances in 3 suggest a SnC multiple bond in the central planar CCPSnC framework.
doi_str_mv 10.1002/anie.199404561
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source Wiley Online Library - AutoHoldings Journals
subjects Chemistry
Exact sciences and technology
Ge, sn, pb derivatives
Organic chemistry
Organometalloidal and organometallic compounds
Preparations and properties
title A Stannanediyl with a TinCarbon Multiple Bond
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