A Stannanediyl with a TinCarbon Multiple Bond

A novel ligand coupling reaction on a low‐coordinate Sn atom occurs in the reaction of the ketene ylide 2 with the stannanediyl 1 (R = 2,4,6‐(CF3)C6H2) almost quantitatively to give 3. The SnC distances in 3 suggest a SnC multiple bond in the central planar CCPSnC framework.

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Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie (International ed.) 1994-03, Vol.33 (4), p.456-458
Hauptverfasser:	Grützmacher, Hansjörg, Deck, Werner, Pritzkow, Hans, Sander, Michael
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Ge, sn, pb derivatives Organic chemistry Organometalloidal and organometallic compounds Preparations and properties
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	A novel ligand coupling reaction on a low‐coordinate Sn atom occurs in the reaction of the ketene ylide 2 with the stannanediyl 1 (R = 2,4,6‐(CF3)C6H2) almost quantitatively to give 3. The SnC distances in 3 suggest a SnC multiple bond in the central planar CCPSnC framework.
ISSN:	0570-0833 1521-3773
DOI:	10.1002/anie.199404561