Organometallic Ferrocenyl Polymers Displaying Tunable Cooperative Interactions between Transition Metal Centers

Organometallic Ferrocenyl Polymers Displaying Tunable Cooperative Interactions between Transition Metal Centers

Due to a dependency on the element in the spacer and its substituents, the extent of the interactions between the ferrocene units of the polymer backbone of 1 and 2 can be varied. The electrochemical behavior of 3 in which the ferrocene units are separated by C2 bridges shows that the cooperative in...

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Veröffentlicht in:Angewandte Chemie (International ed.) 1993-12, Vol.32 (12), p.1709-1711
Hauptverfasser: Foucher, Daniel A., Honeyman, Charles H., Nelson, James M., Tang, Ben Zhong, Manners, Ian
Format: Artikel
Sprache:eng
Schlagworte:
Applied sciences
Exact sciences and technology
Inorganic and organomineral polymers
Physicochemistry of polymers
Properties and characterization
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Zusammenfassung:Due to a dependency on the element in the spacer and its substituents, the extent of the interactions between the ferrocene units of the polymer backbone of 1 and 2 can be varied. The electrochemical behavior of 3 in which the ferrocene units are separated by C2 bridges shows that the cooperative interactions are much less significant for this polymer.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199317091