Giant Organometallic Networks Derived from Ferrocenepolysulfides

Desulfurization with tributylphosphane converts the ferrocenepolysulfide 1 into three‐dimensional network polymers. These consist of ferrocene subunits interconnected by oligosulfide crosslinks. Gel permeation chromatography on an analogous polymerized alkyl derivative of 1 indicates molecular weigh...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 1993-09, Vol.32 (9), p.1319-1321
Hauptverfasser:	Galloway, Collin P., Rauchfuss, Thomas B.
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Inorganic and organomineral polymers Physicochemistry of polymers Preparation
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Desulfurization with tributylphosphane converts the ferrocenepolysulfide 1 into three‐dimensional network polymers. These consist of ferrocene subunits interconnected by oligosulfide crosslinks. Gel permeation chromatography on an analogous polymerized alkyl derivative of 1 indicates molecular weights in excess of 106 Da. •=Fe.
ISSN:	0570-0833 1521-3773
DOI:	10.1002/anie.199313191