Synthesis and Structure of a Trimeric Cyclometalated Coordination Compound with a Hydrophobic Cavity

A molecular tricorn is the best description of complex 2, which arises from ligand 1 and palladium(II) acetate by cyclopalladation and trimerization. Since 2 has a hydrophobic cavity, it may serve as a host for neutral guest molecules, such as acetonitrile. • = Pd.

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Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie (International ed.) 1993-03, Vol.32 (3), p.392-394
Hauptverfasser:	Rüttmann, Stéphane, Williams, Alan F., Bernardinelli, Gérald
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Organic chemistry Organic compounds Organometalloidal and organometallic compounds Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids Transition metals derivatives
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Beschreibung
Zusammenfassung:	A molecular tricorn is the best description of complex 2, which arises from ligand 1 and palladium(II) acetate by cyclopalladation and trimerization. Since 2 has a hydrophobic cavity, it may serve as a host for neutral guest molecules, such as acetonitrile. • = Pd.
ISSN:	0570-0833 1521-3773
DOI:	10.1002/anie.199303921