Hydride Transfer by Hydrido Transition-Metal Complexes. Ionic Hydrogenation of Aldehydes and Ketones, and Structural Characterization of an Alcohol Complex

Hydride Transfer by Hydrido Transition-Metal Complexes. Ionic Hydrogenation of Aldehydes and Ketones, and Structural Characterization of an Alcohol Complex

The rate‐determining step in the hydrogenation of aldehydes or ketones by hydrido complexes and acids appears to be the hydride transfer from the complex to the protonated carbonyl compound. The resulting alcohol is initially bound as ligand, as confirmed by an X‐ray crystal structure analysis of th...

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Veröffentlicht in:Angewandte Chemie International Edition 1992-09, Vol.31 (9), p.1233-1235
Hauptverfasser: Song, Jeong-Sup, Szalda, David J., Bullock, R. Morris, Lawrie, Christophe J. C., Rodkin, Mikhail A., Norton, Jack R.
Format: Artikel
Sprache:eng
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Zusammenfassung:The rate‐determining step in the hydrogenation of aldehydes or ketones by hydrido complexes and acids appears to be the hydride transfer from the complex to the protonated carbonyl compound. The resulting alcohol is initially bound as ligand, as confirmed by an X‐ray crystal structure analysis of the alcohol complex 1.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199212331