Nitrocalix [4]arenes as Molecules for Second-Order Nonlinear Optics

The frequency‐doubling of 820nm laser light is one of the properties of a series of nitrocalix‐[4]arenes making them suitable, in principle, for the construction of a blue laser. Derivative 1 is the most promising, since it displays the greatest hyperpolarizability and the largest dipole moment and...

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Veröffentlicht in:Angewandte Chemie (International ed.) 1992-08, Vol.31 (8), p.1075-1077
Hauptverfasser: Kelderman, Erik, Verboom, Willem, Engbersen, Johan F. J., Reinhoudt, David N., Heesink, Gerard J. T., van Hulst, Niek F., Derhaeg, Lode, Persoons, Andre
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Sprache:eng
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Zusammenfassung:The frequency‐doubling of 820nm laser light is one of the properties of a series of nitrocalix‐[4]arenes making them suitable, in principle, for the construction of a blue laser. Derivative 1 is the most promising, since it displays the greatest hyperpolarizability and the largest dipole moment and is stable as a film in a polymer matrix for long periods.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199210751