New Thermo-Response Dyes: Coloration by the Claisen Rearrangement and Intramolecular Acid-Base Reaction

Applications in information storage and in thermally activated recording systems are anticipated for the novel allyl aryl ether 1. At 180°C 1 rearranges to phenol lactone 2, which in turn undergoes intramolecular proton migration to provide colored 3.

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Veröffentlicht in:Angewandte Chemie International Edition 1992-02, Vol.31 (2), p.204-205
Hauptverfasser: Inouye, Masahiko, Tsuchiya, Kikuo, Kitao, Teijiro
Format: Artikel
Sprache:eng
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Zusammenfassung:Applications in information storage and in thermally activated recording systems are anticipated for the novel allyl aryl ether 1. At 180°C 1 rearranges to phenol lactone 2, which in turn undergoes intramolecular proton migration to provide colored 3.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199202041