Metal Carbonyl Complexes of Sapphyrins
Mono‐ and binuclear Rh and Ir complexes are easily obtained by reaction of sapphyrins with [{RhCl(CO)2}2] and/or [IrCl(CO)2(py)]. In these binuclear complexes (e.g., 1), the two [M(CO)2] fragments are no different sides of the ruffled 22 π‐electron ligands. Complex 1 catayzes the hydrogenation of cy...
Gespeichert in:
| Veröffentlicht in: | Angewandte Chemie International Edition 1991-01, Vol.30 (1), p.91-93 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | Mono‐ and binuclear Rh and Ir complexes are easily obtained by reaction of sapphyrins with [{RhCl(CO)2}2] and/or [IrCl(CO)2(py)]. In these binuclear complexes (e.g., 1), the two [M(CO)2] fragments are no different sides of the ruffled 22 π‐electron ligands. Complex 1 catayzes the hydrogenation of cyclohexenes. |
|---|---|
| ISSN: | 0570-0833 1521-3773 |
| DOI: | 10.1002/anie.199100911 |