Host-Guest Complexes with Closed, Half-open, and Stretched Receptors: Hydrophobic Cavity Effects and Induced Pole-Dipole Interactions

No Absract. The induction of dipoles by N⊕ centers apparently plays an essential role in the binding of lipophilic substrates to receptors. This follows from studies with a closed (type A), a half‐open (type B), and a stretched (type C) receptor and several arenas, and dichloro‐ and diiodomethane....

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Veröffentlicht in:Angewandte Chemie International Edition 1990-10, Vol.29 (10), p.1161-1162
Hauptverfasser: Schneider, Hans-Jörg, Blatter, Thomas, Zimmermann, Patrick
Format: Artikel
Sprache:eng
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Zusammenfassung:No Absract. The induction of dipoles by N⊕ centers apparently plays an essential role in the binding of lipophilic substrates to receptors. This follows from studies with a closed (type A), a half‐open (type B), and a stretched (type C) receptor and several arenas, and dichloro‐ and diiodomethane.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199011611