Host-Guest Complexes with Closed, Half-open, and Stretched Receptors: Hydrophobic Cavity Effects and Induced Pole-Dipole Interactions
No Absract. The induction of dipoles by N⊕ centers apparently plays an essential role in the binding of lipophilic substrates to receptors. This follows from studies with a closed (type A), a half‐open (type B), and a stretched (type C) receptor and several arenas, and dichloro‐ and diiodomethane....
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Veröffentlicht in: | Angewandte Chemie International Edition 1990-10, Vol.29 (10), p.1161-1162 |
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Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | No Absract.
The induction of dipoles by N⊕ centers apparently plays an essential role in the binding of lipophilic substrates to receptors. This follows from studies with a closed (type A), a half‐open (type B), and a stretched (type C) receptor and several arenas, and dichloro‐ and diiodomethane. |
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ISSN: | 0570-0833 1521-3773 |
DOI: | 10.1002/anie.199011611 |