Isolation, Synthesis, and Absolute Configuration of Filbertone - the Principal Flavor Component of the Hazelnut

Isolation, Synthesis, and Absolute Configuration of Filbertone - the Principal Flavor Component of the Hazelnut

The aliphatic enone filbertone 2, the active constituent of the flavor of hazelnuts, is a natural product with low and source‐dependent enantiomeric purity. (ee = 55–63%). To assign the (predominant) absolute configuration (S), (S)‐2 was synthesized from (S)‐1. The configuration of 2 has a decisive...

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Veröffentlicht in:Angewandte Chemie International Edition 1989-08, Vol.28 (8), p.1022-1023
Hauptverfasser: Jauch, Johann, Schmalzing, Dieter, Schurig, Volker, Emberger, Roland, Hopp, Rudolf, Köpsel, Manfred, Silberzahn, Wilhelm, Werkhoff, Peter
Format: Artikel
Sprache:eng
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Zusammenfassung:The aliphatic enone filbertone 2, the active constituent of the flavor of hazelnuts, is a natural product with low and source‐dependent enantiomeric purity. (ee = 55–63%). To assign the (predominant) absolute configuration (S), (S)‐2 was synthesized from (S)‐1. The configuration of 2 has a decisive influence on the smell.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.198910221