catena-Poly[bis-μ-(o-oxyphenyleneoxy)silicon]: Crystal Structure of the Orthosilicate of Catechol

catena-Poly[bis-μ-(o-oxyphenyleneoxy)silicon]: Crystal Structure of the Orthosilicate of Catechol

The title compound 1, which is of special interest because of the postulated square planar SiO4 coordination, forms one‐dimensional infinite polymers with tetrahedrally bound silicon. Both ligands act as bridging functions in the catena structure. The polymer contains ten‐membered C4O4Si2 rings.

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Veröffentlicht in:Angewandte Chemie International Edition 1989-05, Vol.28 (5), p.623-624
Hauptverfasser: Hönle, Wolfgang, Dettlaff-Weglikowska, Urszula, Walz, Leonard, von Schnering, Hans Georg
Format: Artikel
Sprache:eng
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Zusammenfassung:The title compound 1, which is of special interest because of the postulated square planar SiO4 coordination, forms one‐dimensional infinite polymers with tetrahedrally bound silicon. Both ligands act as bridging functions in the catena structure. The polymer contains ten‐membered C4O4Si2 rings.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.198906231