Polyauriomethane Compounds

Polyauriomethane Compounds

The novel compound 1 contains three gold atoms attached to the same carbon atom. All three AuC distances are approximately equal. A further peculiarity: d10‐d10 interactions lead to Au‐Au distances of only ca. 3.2 Å; the tetrahedral angles AuCAu are correspondingly reduced to ca. 100°....

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Veröffentlicht in:Angewandte Chemie International Edition 1988-03, Vol.27 (3), p.419-421
Hauptverfasser: Schmidbaur, Hubert, Scherbaum, Franz, Huber, Brigitte, Müller, Gerhard
Format: Artikel
Sprache:eng
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Zusammenfassung:The novel compound 1 contains three gold atoms attached to the same carbon atom. All three AuC distances are approximately equal. A further peculiarity: d10‐d10 interactions lead to Au‐Au distances of only ca. 3.2 Å; the tetrahedral angles AuCAu are correspondingly reduced to ca. 100°.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.198804191