[(η5-C5Me5)2 Ti2P6], a Distorted Dimetallaphosphacubane

[(η5-C5Me5)2 Ti2P6], a Distorted Dimetallaphosphacubane

Complex 1, obtained as red‐brown, air‐stable crystals, is formed by cothermolysis of [Cp 2*Ti(CO)2] and P4; its NMR spectra differ significantly from those of the triple‐decker complexes [(Cp*M)2(μ,η6−P6)] (M  Mo, W, V). Complex 1 undergoes ready oxidation and ideal reversible reduction. Instead of...

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Veröffentlicht in:Angewandte Chemie International Edition 1987-11, Vol.26 (11), p.1153-1155
Hauptverfasser: Scherer, Otto J., Swarowsky, Herbert, Wolmershäuser, Gotthelf, Kaim, Wolfgang, Kohlmann, Stephan
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container_end_page 1155
container_issue 11
container_start_page 1153
container_title Angewandte Chemie International Edition
container_volume 26
creator Scherer, Otto J.
Swarowsky, Herbert
Wolmershäuser, Gotthelf
Kaim, Wolfgang
Kohlmann, Stephan
description Complex 1, obtained as red‐brown, air‐stable crystals, is formed by cothermolysis of [Cp 2*Ti(CO)2] and P4; its NMR spectra differ significantly from those of the triple‐decker complexes [(Cp*M)2(μ,η6−P6)] (M  Mo, W, V). Complex 1 undergoes ready oxidation and ideal reversible reduction. Instead of a distorted cubane framework, the structure of 1 can be looked upon as a P6 ring in chair conformation with two Cp*Ti “caps.”
doi_str_mv 10.1002/anie.198711531
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title [(η5-C5Me5)2 Ti2P6], a Distorted Dimetallaphosphacubane
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