A Novel Route to Azaalkenylidene-Metal Complexes
The oxime complexes 1 have structures analogous to imine complexes. Such oxime complexes have proven suitable as educts for the synthesis of azaalkenylidene complexes 2 of d‐electronrich transition metals. The cleavage of water from 1 with formal hydridic hydrogen and an N‐bonded OH‐group to give 2...
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| Veröffentlicht in: | Angewandte Chemie International Edition 1987-03, Vol.26 (3), p.248-250 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The oxime complexes 1 have structures analogous to imine complexes. Such oxime complexes have proven suitable as educts for the synthesis of azaalkenylidene complexes 2 of d‐electronrich transition metals. The cleavage of water from 1 with formal hydridic hydrogen and an N‐bonded OH‐group to give 2 proceeds remarkably smoothly [CRR′ = cyclohexylidene or CMe2; {Os} = (C6H6)(PMetBu2)Os]. |
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| ISSN: | 0570-0833 1521-3773 |
| DOI: | 10.1002/anie.198702481 |