Dioxides of C-Amino-Substituted Phosphaalkenes and Phosphaallyl Cations

Dioxides of C-Amino-Substituted Phosphaalkenes and Phosphaallyl Cations

Reaction of the phosphaallyl cation 1 with oxygen transfer agents is reminiscent of enamine epoxidations and the ring‐opening of amino‐oxiranes. Even the perchlorate counterion can effect this oxidation in acetonitrile at 60 °C. No kind of conjugation between the two amidinio moieties is detectable...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 1986-05, Vol.25 (5), p.457-458
Hauptverfasser: Schmidpeter, Alfred, Zirzow, Karl-Heinz, Willhalm, Angela, Holmes, Joan M., Day, Roberta O., Holmes, Robert R.
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Reaction of the phosphaallyl cation 1 with oxygen transfer agents is reminiscent of enamine epoxidations and the ring‐opening of amino‐oxiranes. Even the perchlorate counterion can effect this oxidation in acetonitrile at 60 °C. No kind of conjugation between the two amidinio moieties is detectable in the product 2.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.198604571