Optically Active α-Chloro-(E)-crotylboronate Esters by Allyl Rearrangement
Good chirality transfer to anti‐homoallyl alcohol 3 is observed in the addition of the chiral α‐chlorocrotylboronate 2 to aldehydes. The title reaction 1 → 2 is effected by SOCl2.
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| Veröffentlicht in: | Angewandte Chemie International Edition 1986-02, Vol.25 (2), p.189-190 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Good chirality transfer to anti‐homoallyl alcohol 3 is observed in the addition of the chiral α‐chlorocrotylboronate 2 to aldehydes. The title reaction 1 → 2 is effected by SOCl2. |
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| ISSN: | 0570-0833 1521-3773 |
| DOI: | 10.1002/anie.198601891 |