Hexa-tert-butyldisilane-the Molecule with the Longest SiSi Bond
Steric repulsion of the tert‐butyl groups in the disilane 2 results in a Si‐Si distance about 35 pm greater than that usually found in disilanes. 2 is formed via a radical intermediate upon reaction of nitrosyl cations with 1, MNa, K.
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| Veröffentlicht in: | Angewandte Chemie International Edition 1986-01, Vol.25 (1), p.79-80 |
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| container_issue | 1 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Wiberg, Nils Schuster, Harald Simon, Arndt Peters, Karl |
| description | Steric repulsion of the tert‐butyl groups in the disilane 2 results in a Si‐Si distance about 35 pm greater than that usually found in disilanes. 2 is formed via a radical intermediate upon reaction of nitrosyl cations with 1, MNa, K. |
| doi_str_mv | 10.1002/anie.198600791 |
| format | Article |
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| fulltext | fulltext |
| identifier | ISSN: 0570-0833 |
| ispartof | Angewandte Chemie International Edition, 1986-01, Vol.25 (1), p.79-80 |
| issn | 0570-0833 1521-3773 |
| language | eng |
| recordid | cdi_crossref_primary_10_1002_anie_198600791 |
| source | Wiley Online Library Journals Frontfile Complete |
| title | Hexa-tert-butyldisilane-the Molecule with the Longest SiSi Bond |
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