Mechanism of Purpurogallin Formation: An Adduct from 3-Hydroxy-o-benzoquinone and 4,5-Dimethyl-o-benzoquinone
The adduct 2 has long been postulated as an intermediate in the formation of purpurogallin 1 from pyrogallol. The adduct 5, formed from the o‐benzoquinones 3 and 4, exhibits extensive structural analogy to 2 and thus supports previous conceptions on the mechanism of purpurogallin formation.
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| Veröffentlicht in: | Angewandte Chemie International Edition 1985-03, Vol.24 (3), p.224-225 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The adduct 2 has long been postulated as an intermediate in the formation of purpurogallin 1 from pyrogallol. The adduct 5, formed from the o‐benzoquinones 3 and 4, exhibits extensive structural analogy to 2 and thus supports previous conceptions on the mechanism of purpurogallin formation. |
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| ISSN: | 0570-0833 1521-3773 |
| DOI: | 10.1002/anie.198502241 |