Facile Synthesis of Highly Reactive Ferracycloalkanes

Facile Synthesis of Highly Reactive Ferracycloalkanes

Nucleophilic elimination‐cycloaddition is a suitable method for the synthesis of cyclic organoiron compounds. 2a, L  CO, is extremely volatile. In the case of the more stable 2b, L  PPh3, enantiomers have been found in the crystal. 3a, L  CO (already known), and 3b, L  PPh3, are likewise readily...

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Veröffentlicht in:Angewandte Chemie International Edition 1984-09, Vol.23 (9), p.711-712
Hauptverfasser: Lindner, Ekkehard, Schauss, Eckard, Hiller, Wolfgang, Fawzi, Riad
Format: Artikel
Sprache:eng
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Zusammenfassung:Nucleophilic elimination‐cycloaddition is a suitable method for the synthesis of cyclic organoiron compounds. 2a, L  CO, is extremely volatile. In the case of the more stable 2b, L  PPh3, enantiomers have been found in the crystal. 3a, L  CO (already known), and 3b, L  PPh3, are likewise readily accessible in this way.—Metallacyclopentanes such as 2 occur as highly reactive intermediates in numerous metal‐catalyzed reactions.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.198407111