Synthesis of a Porphyrin Sandwiched between Two Parallel p-Benzoquinone Units

Synthesis of a Porphyrin Sandwiched between Two Parallel p-Benzoquinone Units

p‐Benzoquinone‐porphyrin‐p‐benzoquinone is the layer sequence in the sandwich compound shown on the cover. This compound is formed in 0.1% yield from 1, RCHO and pyrrole in refluxing propionic acid. The four bridges in the sandwich compound are short and contain no heteroatoms. It may serve as a mo...

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Veröffentlicht in:Angewandte Chemie International Edition 1984-08, Vol.23 (8), p.623-625
Hauptverfasser: Weiser, Jürgen, Staab, Heinz A.
Format: Artikel
Sprache:eng
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Zusammenfassung:p‐Benzoquinone‐porphyrin‐p‐benzoquinone is the layer sequence in the sandwich compound shown on the cover. This compound is formed in 0.1% yield from 1, RCHO and pyrrole in refluxing propionic acid. The four bridges in the sandwich compound are short and contain no heteroatoms. It may serve as a model for the study of biochemically important electron‐transfer reactions.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.198406231