A New Cationic Hydrido-Bridged Rhodium(I)-Iridium(III) Complex

A New Cationic Hydrido-Bridged Rhodium(I)-Iridium(III) Complex

The new complex (1), whose dark green crystals are stable in air, contains a five‐coordinate rhodium(I) and a six‐coordinate irid‐ium(III) with three bridging hydride ligands. (1) can be prepared by reaction of [Rh(di‐phos)(MeOH)2][BF4] with mer‐[IrH3(PEt3)3] and subsequent precipitation with NaBPh4...

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Veröffentlicht in:Angewandte Chemie International Edition 1981-11, Vol.20 (11), p.958-959
Hauptverfasser: Albinati, Alberto, Musco, Alfredo, Naegeli, Ralph, Venanzi, Luigi M.
Format: Artikel
Sprache:eng
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Zusammenfassung:The new complex (1), whose dark green crystals are stable in air, contains a five‐coordinate rhodium(I) and a six‐coordinate irid‐ium(III) with three bridging hydride ligands. (1) can be prepared by reaction of [Rh(di‐phos)(MeOH)2][BF4] with mer‐[IrH3(PEt3)3] and subsequent precipitation with NaBPh4.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.198109581