A Diorganotin Oxide with a Planar Tin-Chalcogen Six-Membered Ring

The first compound containing a planar (SnO)3‐ring is a form of (1) readily soluble in organic solvents, even in the cold; (1) was obtained on reaction of tBu2SnCl2 with NaOH in boiling toluene. So far only sparingly soluble (1)–probably polymeric in the solid state–was known.

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Veröffentlicht in:Angewandte Chemie International Edition 1981-06, Vol.20 (6-7), p.591-591
Hauptverfasser: Puff, Heinrich, Schuh, Willi, Sievers, Rolf, Zimmer, René
Format: Artikel
Sprache:eng
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Zusammenfassung:The first compound containing a planar (SnO)3‐ring is a form of (1) readily soluble in organic solvents, even in the cold; (1) was obtained on reaction of tBu2SnCl2 with NaOH in boiling toluene. So far only sparingly soluble (1)–probably polymeric in the solid state–was known.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.198105911