N-Ethynylamines of the Type RNHCCH

The first N‐ethynylamines such as (2) with secondary amino groups were obtained by flash vacuum pyrolysis of (1) in a special apparatus fitted with facilities for IR spectroscopy. (2) is transformed into N‐phenylketenimine at ‐ 70°C.

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Veröffentlicht in:Angewandte Chemie International Edition 1980-09, Vol.19 (9), p.720-721
Hauptverfasser: Winter, Hans-Wilhelm, Wentrup, Curt
Format: Artikel
Sprache:eng
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Zusammenfassung:The first N‐ethynylamines such as (2) with secondary amino groups were obtained by flash vacuum pyrolysis of (1) in a special apparatus fitted with facilities for IR spectroscopy. (2) is transformed into N‐phenylketenimine at ‐ 70°C.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.198007201