Ternary Rhenium Sulfides with [Re6S8]-Clusters

The first clusters to contain Re6 units are present in compounds (1) to (3). The six Re atoms form an octahedron with eight S atoms distributed over the faces. Other ternary sulfides of type AxMySz have chain or layer structures.

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Veröffentlicht in:Angewandte Chemie International Edition 1978-05, Vol.17 (5), p.368-368
Hauptverfasser: Spangenberg, Manfred, Bronger, Welf
Format: Artikel
Sprache:eng
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Zusammenfassung:The first clusters to contain Re6 units are present in compounds (1) to (3). The six Re atoms form an octahedron with eight S atoms distributed over the faces. Other ternary sulfides of type AxMySz have chain or layer structures.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.197803681