Palladium‐Catalyzed (4+2) Annulations of Silacyclobutanes and Activated Ketones

Presented herein is a palladium‐catalyzed (4+2) annulation reaction between silacyclobutanes and activated ketones, which features advantages of operation simplicity, broad substrate scope and good functionality tolerance. A diversity of oxasilacyclohexanes were straightforwardly constructed in high...

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Veröffentlicht in:Asian journal of organic chemistry 2024-11
Hauptverfasser: Song, Zhao‐Li, Zheng, Jia‐Le, Chen, Zhi‐Chao, Du, Wei, Song, Zhenlei, Chen, Ying‐Chun
Format: Artikel
Sprache:eng
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Zusammenfassung:Presented herein is a palladium‐catalyzed (4+2) annulation reaction between silacyclobutanes and activated ketones, which features advantages of operation simplicity, broad substrate scope and good functionality tolerance. A diversity of oxasilacyclohexanes were straightforwardly constructed in high yields.
ISSN:2193-5807
2193-5815
DOI:10.1002/ajoc.202400536