Cs 2 CO 3 ‐Promoted Michael Addition‐[2,3]‐Sigmatropic Rearrangement Domino Reaction: Facile Synthesis of a 3‐Substituted Indoles Bearing a Homoallyl Sulfide Moiety
A Cs 2 CO 3 ‐promoted Michael addition‐[2,3]‐sigmatropic rearrangement domino reaction between arenesulfonylindole and sulfur ylide has been developed. This reaction affords a facile method for the synthesis of 3‐substituted indoles with a homoallyl sulfide moiety. In this domino sequence, two C−C b...
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| Veröffentlicht in: | Asian journal of organic chemistry 2016-11, Vol.5 (11), p.1309-1313 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A Cs
2
CO
3
‐promoted Michael addition‐[2,3]‐sigmatropic rearrangement domino reaction between arenesulfonylindole and sulfur ylide has been developed. This reaction affords a facile method for the synthesis of 3‐substituted indoles with a homoallyl sulfide moiety. In this domino sequence, two C−C bonds and one C−C bond cleavage were formed. |
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| ISSN: | 2193-5807 2193-5815 |
| DOI: | 10.1002/ajoc.201600343 |