Chemical Insight into the Structure and Formation of Coke on PtSn Alloy during Propane Dehydrogenation
Propane dehydrogenation (PDH) catalyzed by PtSn/Al2O3 is a vital industrial process for producing propylene, a significant building block in the chemical industry. However, coke produced in the process deactivates the catalyst and the energy‐intensive regeneration procedures can produce considerable...
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Veröffentlicht in: | Advanced sustainable systems (Online) 2020-09, Vol.4 (9), p.n/a |
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Sprache: | eng |
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Zusammenfassung: | Propane dehydrogenation (PDH) catalyzed by PtSn/Al2O3 is a vital industrial process for producing propylene, a significant building block in the chemical industry. However, coke produced in the process deactivates the catalyst and the energy‐intensive regeneration procedures can produce considerable CO2 emission. In this work, coke on the spent catalysts is analyzed by thermogravimetric‐mass spectra, Raman spectra, 1H solid NMR spectra, and infrared spectra. Several C3 species, including propyl, propylidene and propylidyne are found on the surface of the PtSn alloy. Several reaction pathways are investigated by density functional theory (DFT) calculations. It is also found that this coke can be hydrogenated to propylene in the PDH process. These results could provide theoretical guidance for optimizing process parameters in industry.
Several C3 species are determined to coke at the surface of PtSn alloy during propane dehydrogenation. Their structure and formation are analyzed in detail. And this distinctive coke can be hydrogenated to propylene in a dehydrogenation reaction. This finding could provide theoretical guidance for designing more efficient catalysts and optimizing parameters in the industrial process. |
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ISSN: | 2366-7486 2366-7486 |
DOI: | 10.1002/adsu.202000092 |