Silver‐Catalyzed Radical Cascade Cyclization of Unactivated Alkenes towards Cyclopenta[c]quinolines

Silver‐Catalyzed Radical Cascade Cyclization of Unactivated Alkenes towards Cyclopenta[c]quinolines

A convenient radical cascade cyclization of aniline‐linked 1,7‐enynes with 1,3‐dicarbonyl compounds was developed to synthesize cyclopenta[c]quinolines in the presence of AgNO3/K2S2O8. A wide range of cyclopenta[c]quinolines were prepared in moderate to excellent yields.

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Veröffentlicht in:Advanced synthesis & catalysis 2019-10, Vol.361 (19), p.4483-4488
Hauptverfasser: Sun, Kai, Si, Ya‐Feng, Chen, Xiao‐Lan, Lv, Qi‐Yan, Jiang, Nan, Wang, Shan‐Shan, Peng, Yu‐Yu, Qu, Ling‐Bo, Yu, Bing
Format: Artikel
Sprache:eng
Schlagworte:
1,3-Dicarbonyl compound
Cyclopenta[c]quinolines
Radical cascade reaction
Unactivated alkenes
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Zusammenfassung:A convenient radical cascade cyclization of aniline‐linked 1,7‐enynes with 1,3‐dicarbonyl compounds was developed to synthesize cyclopenta[c]quinolines in the presence of AgNO3/K2S2O8. A wide range of cyclopenta[c]quinolines were prepared in moderate to excellent yields.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201900691