Synthesis of N-Alkoxy Amines via Catalytic Oxidation of Hydrocarbons

Sterically hindered N‐alkoxy amines 3 are synthesized in good yields by coupling nitroxides 2 with hydrocarbyl radicals generated in situ by t‐BuOOH hydrogen ion from hydrocarbons. The reaction is catalyzed by copper halides as well as by onium iodides.

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Bibliographische Detailangaben
Veröffentlicht in:	Advanced synthesis & catalysis 2004-04, Vol.346 (5), p.554-560
Hauptverfasser:	Kirner, Hans-J., Schwarzenbach, Franz, van der Schaaf, Paul A., Hafner, Andreas, Rast, Valérie, Frey, Markus, Nesvadba, Peter, Rist, Guenther
Format:	Artikel
Sprache:	eng
Schlagworte:	copper hydrocarbons N-alkoxy amines nitroxides oxidation phase-transfer catalysis radical reactions TEMPO tert-butyl hydroperoxide
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Beschreibung
Zusammenfassung:	Sterically hindered N‐alkoxy amines 3 are synthesized in good yields by coupling nitroxides 2 with hydrocarbyl radicals generated in situ by t‐BuOOH hydrogen ion from hydrocarbons. The reaction is catalyzed by copper halides as well as by onium iodides.
ISSN:	1615-4150 1615-4169
DOI:	10.1002/adsc.200303194