Enantioselective Hydrogenation of β-Acylamino Acrylates Catalyzed by Rhodium(I)-Monophosphite Complexes

Enantioselective Hydrogenation of β-Acylamino Acrylates Catalyzed by Rhodium(I)-Monophosphite Complexes

Chiral rhodium(I) complexes bearing monophosphite ligands, prepared from chiral Binol and (L)‐menthol, were found to be efficient catalysts for the asymmetric hydrogenation of β‐acylamino acrylates with ee values up to 94%.

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Veröffentlicht in:Advanced synthesis & catalysis 2004-01, Vol.346 (1), p.33-36
Hauptverfasser: Jerphagnon, Thomas, Renaud, Jean-Luc, Demonchaux, Patrice, Ferreira, Amadéo, Bruneau, Christian
Format: Artikel
Sprache:eng
Schlagworte:
enantioselective catalysis
hydrogenation
monophosphite ligands
rhodium
β-acylamino acrylates
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Zusammenfassung:Chiral rhodium(I) complexes bearing monophosphite ligands, prepared from chiral Binol and (L)‐menthol, were found to be efficient catalysts for the asymmetric hydrogenation of β‐acylamino acrylates with ee values up to 94%.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.200303144