Charge transfer complexes of (TTFTe)2: Preparation, structure, and electrical conductivity

Charge transfer complexes of (TTFTe)2: Preparation, structure, and electrical conductivity

Organic metals based on organo‐tellurium units are of particular interest because of the increased orbital overlap in these systems which leads to favorable conditions for conductivity. The figure shows the crystal structure of (TTFTe)2 · TCNQ, which is semiconducting, while the (TTFTe)2 · (TCNQ)2 c...

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Veröffentlicht in:Advanced materials (Weinheim) 1994-10, Vol.6 (10), p.758-761
Hauptverfasser: Becker, James Y., Bernstein, Joel, Dayan, Moshe, Ellern, Arkady, Shahal, Leah
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
Miscellaneous
Organic chemistry
Organometalloidal and organometallic compounds
Preparations and properties
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Zusammenfassung:Organic metals based on organo‐tellurium units are of particular interest because of the increased orbital overlap in these systems which leads to favorable conditions for conductivity. The figure shows the crystal structure of (TTFTe)2 · TCNQ, which is semiconducting, while the (TTFTe)2 · (TCNQ)2 complex has a conductivity of 8.2 S/cm at room temperature.
ISSN:0935-9648
1521-4095
DOI:10.1002/adma.19940061009