Porous Chromium Terephthalate MIL-101 with Coordinatively Unsaturated Sites: Surface Functionalization, Encapsulation, Sorption and Catalysis

Porous Chromium Terephthalate MIL-101 with Coordinatively Unsaturated Sites: Surface Functionalization, Encapsulation, Sorption and Catalysis

Recent ideas concerning site‐selective functionalization of chromium terephtha‐late MIL‐101 are discussed, focusing on the utilization of unsaturated Cr(III) sites (see image). Recent advances in synthesis, selective surface functionalization, outstanding sorption properties, encapsulation of nanoob...

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Veröffentlicht in:Advanced functional materials 2009-05, Vol.19 (10), p.1537-1552
Hauptverfasser: Hong, Do-Young, Hwang, Young Kyu, Serre, Christian, Férey, Gérard, Chang, Jong-San
Format: Artikel
Sprache:eng
Schlagworte:
catalysis
chromium terephthalate
functionalization
metal-organic frameworks
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Zusammenfassung:Recent ideas concerning site‐selective functionalization of chromium terephtha‐late MIL‐101 are discussed, focusing on the utilization of unsaturated Cr(III) sites (see image). Recent advances in synthesis, selective surface functionalization, outstanding sorption properties, encapsulation of nanoobjects, and catalytic applications in MIL‐101 are also discussed.
ISSN:1616-301X
1616-3028
DOI:10.1002/adfm.200801130