Spray‐Coating of Superhydrophobic Coatings for Advanced Applications

Superhydrophobic coatings are widely applicable, e.g., as self‐cleaning surfaces or water–oil separation membranes, yet their wider usage is impeded due to costs of fabrication, size, or substrate limitation. Spray‐coating is a versatile coating procedures and might offer a good solution for the fabrication of these superhydrophobic coatings, due to the fact that coatings can be fabricated on various materials in a simple, fast, and inexpensive manner. Most procedures rely on hybrid coatings of hydrophobized nanoparticles and a polymeric matrix, which have several drawbacks including the easy loss of nanoparticles and difficult waste handling. Here, the fabrication of the superhydrophobic material, called Fluoropor, for the first time, by spray‐coating on various substrates including metals, tissues, concrete, and glass is presented. It is fabricated by spray‐coating a mixture of a highly fluorinated monomer blended with porogens followed by photopolymerization. The superhydrophobicity of the material relies on the porous structure on the micro‐/nanoscale across the bulk material and does not require any nanoparticles. Excellent self‐cleaning ability of these coatings, resistance against thermal and abrasive impact, and their application as oil–water separation membranes are shown. This versatile applicability is highly promising for real‐world application as self‐cleaning coatings or oil–water separating membranes. Superhydrophobic large‐scale surfaces of bulk‐porous polymer foams are spray‐coated. The resistance to heat and abrasion of the coatings as well as the ability to spray‐coat different classes of substrates make these highly promising for real‐world application. Self‐cleaning ability and oil–water separation are shown in this work underlining the high potential of applicability.