Syntheses of 3-Oxa-OPC and 2-Fluoro-OPC Homologues

Synopsis: 3-Oxa-OPC and 2-fluoro-OPC homologues which do not undergo β-oxidation were synthesized from esters of odd-numbered OPC homologues by a short-step procedure. The 3-oxa-OPC homologues were synthesized via etherification of an alcohol with tert-butyl bromoacetate under phase-transfer conditi...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Bioscience, biotechnology, and biochemistry biotechnology, and biochemistry, 1998, Vol.62 (4), p.689-694, Article 689
Hauptverfasser:	TOSHIMA, Hiroaki, FUJINO, Yumiko, ICHIHARA, Akitami, KODA, Yasunori, KIKUTA, Yoshio
Format:	Artikel
Sprache:	eng
Schlagworte:	Alicyclic compounds Alicyclic compounds, terpenoids, prostaglandins, steroids Chemistry Exact sciences and technology jasmonic acid jasmonoid octadecanoid OPC Organic chemistry Preparations and properties β-oxidation
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Synopsis: 3-Oxa-OPC and 2-fluoro-OPC homologues which do not undergo β-oxidation were synthesized from esters of odd-numbered OPC homologues by a short-step procedure. The 3-oxa-OPC homologues were synthesized via etherification of an alcohol with tert-butyl bromoacetate under phase-transfer conditions. The 2-fluoro-OPC homologues were synthesized via the addition of the trichloromethyl anion to an aldehyde and subsequent fluorination.
ISSN:	0916-8451 1347-6947
DOI:	10.1271/bbb.62.689